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Product Details
1,3,5-Tris(bromomethyl)benzene Good Supplier In Bulk Supply High Purity 18226-42-1
- Molecular Formula:C9H9Br3
- Molecular Weight:356.882
- Appearance/Colour:White to pale yellow solid
- Vapor Pressure:7.93E-05mmHg at 25°C
- Melting Point:94-99 °C
- Refractive Index:1.641
- Boiling Point:352.2 °C at 760 mmHg
- Flash Point:162.5 °C
- PSA：0.00000
- Density:2.005 g/cm3
- LogP:4.37130
1,3,5-Tris(bromomethyl)benzene(Cas 18226-42-1) Usage
|
General Description |
1,3,5-Tris(bromomethyl)benzene has three bromo substituents around an aromatic ring that can be used as a cross-linker. It is mainly utilized in the synthesis of ligands and dendrimeric monomers. |
InChI:InChI=1/C9H9Br3/c10-4-7-1-8(5-11)3-9(2-7)6-12/h1-3H,4-6H2
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18226-42-1 Process route
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-
42268-88-2
1,3-dimethyl 5-(bromomethyl)benzene-1,3-dicarboxylate
-
-
18226-42-1
1,3,5-Tris(bromomethyl)benzene
| Conditions | Yield |
|---|---|
|
Multi-step reaction with 3 steps
1: 1.) Na / 2.) reflux, 4 h
2: 75.5 percent / LiAlH4 / tetrahydrofuran / 1.) -10 deg C, 1 h, 2.) r.t., 1 h
3: PBr3 / CHCl3 / 2 h / Ambient temperature
With
lithium aluminium tetrahydride; sodium; phosphorus tribromide;
In
tetrahydrofuran; chloroform;
|
-
-
108-67-8
1,3,5-trimethyl-benzene
-
-
18226-42-1
1,3,5-Tris(bromomethyl)benzene
| Conditions | Yield |
|---|---|
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
tetrachloromethane;
at 70 ℃;
for 6h;
|
96% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
tetrachloromethane;
at 70 ℃;
for 0.6h;
Heating;
|
96% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
tetrachloromethane;
at 70 ℃;
for 12h;
|
95% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
tetrachloromethane;
at 70 ℃;
for 12h;
|
92% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
benzene;
at 80 ℃;
for 2h;
|
92% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
benzene;
at 76 ℃;
|
91% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
benzene;
at 95 ℃;
for 0.5h;
|
88% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
tetrachloromethane;
at 90 ℃;
for 14h;
Inert atmosphere;
|
81% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
tetrachloromethane;
at 90 ℃;
for 14h;
Inert atmosphere;
|
81% |
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
In
benzene;
for 10h;
Reflux;
|
79% |
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
In
benzene;
for 10h;
Reflux;
|
79% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
chloroform;
at 70 ℃;
for 6h;
Inert atmosphere;
|
72% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
tetrachloromethane;
at 70 ℃;
for 6h;
|
59% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
benzene;
at 95 ℃;
for 12h;
|
57.1% |
|
1,3,5-trimethyl-benzene;
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
tetrachloromethane;
Heating;
With
Diethyl phosphonate; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran;
at 25 ℃;
for 29h;
|
52% |
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
In
tetrachloromethane;
for 4h;
Heating;
|
51% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
tetrachloromethane;
for 16h;
Heating;
irradiation;
|
43% |
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
In
tetrachloromethane;
at 90 ℃;
for 40h;
|
40% |
|
With
N-Bromosuccinimide;
|
35% |
|
With
N-Bromosuccinimide;
In
tetrachloromethane;
Irradiation;
|
30% |
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
In
tetrachloromethane;
|
30% |
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
In
tetrachloromethane;
at 85 ℃;
for 15h;
|
19.3% |
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
In
ethyl acetate;
Reflux;
|
17% |
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
benzene;
at 95 ℃;
for 3.5h;
|
16% |
|
With
N-Bromosuccinimide; azobisisobutyronitrile;
In
tetrachloromethane;
at 76 ℃;
for 24h;
|
7% |
|
With
bromine;
|
|
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
In
Methyl formate;
at 20 ℃;
for 14h;
|
|
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
tetrachloromethane;
for 96h;
Heating;
UV-irradiation;
|
2.5 g |
|
With
N-Bromosuccinimide;
2,2'-azobis(isobutyronitrile);
In
tetrachloromethane;
Heating;
|
8.91 g |
|
Multi-step reaction with 2 steps
1: 78 percent / NBS; BPO / benzene / 12 h / 85 °C
2: 78 percent / NBS; BPO / benzene / 12 h / 85 °C
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
benzene;
|
|
|
Multi-step reaction with 2 steps
1: bromine / 160 °C / Irradiation.UV-Licht
2: tetrachloromethane; dibenzoyl peroxide; <α,α'>azoisobutyronitrile; N-bromo-succinimide
With
tetrachloromethane; N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); bromine; dibenzoyl peroxide;
|
|
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
benzene;
Reflux;
|
|
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
In
dichloromethane;
for 4.33333h;
Heating / reflux;
|
|
|
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
carbonic acid dimethyl ester;
at 110 ℃;
for 15h;
Inert atmosphere;
|
|
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
|
|
|
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile);
In
tetrachloromethane;
|
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1,3,5-Tris(bromomethyl)benzene
CAS:18226-42-1
Purity:99%
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