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p-Nitrobenzoic acid

  • Cas number：62-23-7
  • purity：99%
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Product Details

Manufacturers supply cost-effective and customizable p-Nitrobenzoic acid 62-23-7

  • Molecular Formula: C7H5NO4
  • Molecular Weight: 167.121
  • Appearance/Colour: light yellow crystalline powder 
  • Vapor Pressure: 8.78E-06mmHg at 25°C 
  • Melting Point: 237-240 °C(lit.) 
  • Refractive Index: 1.6280 (estimate) 
  • Boiling Point: 359.1 °C at 760 mmHg 
  • PKA: 3.41(at 25℃) 
  • Flash Point: 166.5 °C 
  • PSA： 83.12000 
  • Density: 1.468 g/cm3 
  • LogP: 1.81620 

p-Nitrobenzoic acid(Cas 62-23-7) Usage

Synthesis Reference(s)

Tetrahedron Letters, 26, p. 2387, 1985 DOI: 10.1016/S0040-4039(00)94834-2Journal of the American Chemical Society, 72, p. 5012, 1950 DOI: 10.1021/ja01167a051

Air & Water Reactions

Insoluble in water.

Reactivity Profile

p-Nitrobenzoic acid is incompatible with strong oxidizers. p-Nitrobenzoic acid is also incompatible with strong bases (potassium hydroxide). p-Nitrobenzoic acid may react with cyanides.

Fire Hazard

p-Nitrobenzoic acid is combustible.

Purification Methods

Purify it as for 3-nitrobenzoic acid above. The amide has m 201.6o (from H2O). [Beilstein 9 III 1537, 9 IV 1072.]

Definition

ChEBI: A nitrobenzoic acid having the nitro group at the 4-position.

General Description

Odorless pale yellow crystals.

InChI:InChI=1/C7H5NO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4H,(H,9,10)/p-1

62-23-7 Relevant articles

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Wardner,Lowy

, p. 2510,2514 (1932)

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1,4-DIAMINO-1,4-DIDEOXY-D-GALACTITOL AND 1,5-DIAMINO-1,5-DIDEOXY-L-ALTRITOL

Kuszmann Janos

, p. 25 - 38 (1986)

The mesyloxy group of 1-azido-1-deoxy-4-...

Studies on a dithiane-protected benzoin photolabile safety catch linker for solid-phase synthesis

Hong Boon Lee,Balasubramanian

, p. 3454 - 3460 (1999)

Substituted benzoinyl systems 8a-g, diff...

Disproportionation of 4-Nitroacetophenone to 4-Aminoacetophenone and 4-Nitrobenzoic Acid

Wan, Peter,Xu, Xigen

, p. 4473 - 4474 (1989)

-

Synthesis of 18O-labelled alcohols from unlabelled alcohols

Beddoe, Rhydian H.,Edwards, Daniel C.,Goodman, Louis,Sneddon, Helen F.,Denton, Ross M.

, p. 6480 - 6483 (2020)

The synthesis of primary, secondary and ...

2-(5-Arylterphenyl-4-yl)quinolines from 2-methylquinoline and 1-(het)aryl-3-phenylprop-2-yn-1-ones in just a one step: A miracle of molecular interplay

Trofimov, Boris A.,Belyaeva, Kseniya V.,Nikitina, Lina P.,Afonin, Andrei V.,Vashchenko, Alexander V.

, p. 267 - 269 (2018)

2-Methylquinoline reacts with 1-(het)ary...

Sodium percarbonate: A convenient reagent for the thermal and sonic oxidative cleavage of α-haloketones

Yang,Cao,Kabalka

, p. 3695 - 3699 (1995)

Sodium percarbonate has been found to be...

Novel rearrangement of 4-aroyloxy-3-bromomethyl-2-isoxazolines to 3-aroyloxymethylisoxazoles and a mechanistic study

Chang,Kim

, p. 8499 - 8503 (2000)

Treatment of 4-aroyloxy-3-bromomethyl- a...

Use of ozone for preparing 4-nitrobenzoic acid in a closed process cycle

Galstyan,Tyupalo,Patapenko,Andreev

, p. 1777 - 1779 (2001)

The possibility of preparing 4-nitrobenz...

Transformation of Thioacids into Carboxylic Acids via a Visible-Light-Promoted Atomic Substitution Process

Fu, Qiang,Liang, Fu-Shun,Lou, Da-Wei,Pan, Gao-Feng,Wang, Rui,Wu, Min,Xie, Kai-Jun

supporting information, p. 2020 - 2024 (2022/03/31)

A visible-light-promoted atomic substitu...

Merging N-Hydroxyphthalimide into Metal-Organic Frameworks for Highly Efficient and Environmentally Benign Aerobic Oxidation

Wang, Man,Liang, Gan,Wang, Yunhao,Fan, Tao,Yuan, Baoling,Liu, Mingxian,Yin, Ying,Li, Liangchun

supporting information, p. 9674 - 9685 (2021/06/09)

Two highly efficient metal-organic frame...

Green synthesis of a vanadium(V) Schiff base complex by grinding method: study on its catalytic and anti-bacterial activity

Boruah, Jeena Jyoti,Bhatt, Zankhana S.,Nathani, Chirag R.,Bambhaniya, Vaishali J.,Guha, Ankur Kanti,Das, Siva Prased

, p. 2055 - 2068 (2021/06/27)

A facile protocol was developed for the ...

Acetyl nitrate mediated conversion of methyl ketones to diverse carboxylic acid derivatives

Bernard, Josephine,Capilato, Joseph N.,Hoy, Erik P.,Mattiucci, Joseph,Pellegrinelli, Peter J.,Perez, Lark J.,Philippi, Shane,Schnorbus, Logan

, p. 5298 - 5302 (2021/06/30)

The development of a novel acetyl nitrat...

62-23-7 Process route

1-methyl-4-nitrosobenzene
623-11-0

1-methyl-4-nitrosobenzene

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33322-37-1

4-nitro-benzoic acid bromoamide

4-nitro-aniline
100-01-6,104810-17-5

4-nitro-aniline

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

Conditions
Conditions Yield
at 30 ℃; Kinetics;
4-nitro-benzaldehyde-(<i>O</i>-[1]naphthylcarbamoyl-(<i>Z</i>)-oxime ); α-naphthylcarbamic acid-derivative of 4-nitro-β-benzaldoxime

4-nitro-benzaldehyde-(O -[1]naphthylcarbamoyl-(Z )-oxime ); α-naphthylcarbamic acid-derivative of 4-nitro-β-benzaldoxime

furan-2,3,5(4H)-trione pyridine (1:1)

furan-2,3,5(4H)-trione pyridine (1:1)

1,3-dinaphthalen-1-ylurea
607-56-7

1,3-dinaphthalen-1-ylurea

1-amino-naphthalene
134-32-7

1-amino-naphthalene

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

Conditions
Conditions Yield

62-23-7 Upstream products

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    110-86-1

    pyridine

  • 1712-84-1
    1712-84-1

    p-nitrobenzoyl peroxide

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    phenyl benzyl ketone

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    619-73-8

    4-nitrobenzyl chloride

62-23-7 Downstream products

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    99841-82-4

    2-(4-nitro-benzoylamino)-butan-1-ol

  • 75474-05-4
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    benzoic-p-nitrobenzoic anhydride

  • 902-47-6
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    p-nitrobenzoic anhydride

  • 122-04-3
    122-04-3

    4-nitro-benzoyl chloride

p-Nitrobenzoic acid

CAS:62-23-7

Purity:99%

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